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Which key aromatic and active compounds does this valerian root oil contain?

Valerian root oil is chemically defined by sesquiterpenes (valeranone), monoterpene esters (bornyl acetate), and valerenic acids — the latter being the signature GABA-modulating active of European valerian.

Key Compounds & Specifications

CompoundRole / SpecificationStandard
Camphene9%–29% (mandatory fingerprint)T/CAFFCI 70-2023
Bornyl acetate21%–41% (mandatory fingerprint)T/CAFFCI 70-2023
ValeranoneSignature woody-rooty sesquiterpene ketone; aroma-definingISO 4720 / literature
Valerenic acidsGABA receptor modulators; active sedative markersEMA monograph; USP: ≥ 0.05% in root; EP: ≥ 0.17% in root
Isovaleric acid & estersMusky-animalic base noteLiterature
Essential oil content (root)≥ 0.5% mL/gEP Valerianae radix
  • Key note: Chinese V. jatamansi (Zhi Zhu Xiang) typically does NOT contain valerenic acid — that is the main chemical difference from European V. officinalis
  • GC-MS identified 98 components in SFE-CO2 extract vs 67 in steam-distilled oil (47 shared) — the CO2 grade is richer in heavier sesquiterpenes
  • Bornyl acetate purity can reach 77.46% after molecular distillation (Li et al. 2017)
  • A full GC-MS composition report accompanies every batch COA; camphene and bornyl acetate ranges are verified per T/CAFFCI 70-2023

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This article was published on 2026-09-07, and last updated on 2026-09-07. The article will be continuously updated.